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Khnayzer Rony S.pdf (6.42 MB)
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Abstract Header
Photocatalytic Water Splitting: Materials Design and High-Throughput Screening of Molecular Compositions
Author Info
Khnayzer, Rony S.
Permalink:
http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1368627386
Abstract Details
Year and Degree
2013, Doctor of Philosophy (Ph.D.), Bowling Green State University, Photochemical Sciences.
Abstract
Due to the expected increases on energy demand in the near future, the development of new catalytic molecular compositions and materials capable of directly converting water, with the aid of solar photons, into hydrogen becomes obviated. Hydrogen is a combustible fuel and precious high-energy feedstock chemical. However, for the water-splitting reaction to proceed efficiently and economically enough for large-scale application, efficient light-absorbing sensitizers and water splitting catalysts are required. To study the kinetics of the water reduction reaction, we have used titania (TiO
2
) nanoparticles as a robust scaffold to photochemically grow platinum (Pt) nanoparticles from a unique surface-anchored molecular precursor Pt(dcbpy)Cl
2
[dcbpy = 4,4`-dicarboxylic acid-2,2`-bipyridine]. The hybrid Pt/TiO
2
nanomaterials obtained were shown to be a superior water reduction catalyst (WRC) in aqueous suspensions when compared with the benchmark platinized TiO
2
. In addition, cobalt phosphate (CoPi) water oxidation catalyst (WOC) was photochemically assembled on the surface of TiO
2
, and its structure and mechanism of activity showed resemblance to the established electrochemically grown CoPi material. Both WRC and WOC described above possessed near unity Faradaic efficiency for hydrogen and oxygen production respectively, and were fully characterized by electron microscopy, x-ray absorption spectroscopy, electrochemistry and photochemistry. While there are established materials and molecules that are able to drive water splitting catalysis, some of these efficient semiconductors, including titanium dioxide (TiO
2
) and tungsten trioxide (WO
3
), are only able to absorb high-energy (ultraviolet or blue) photons. This high-energy light represents merely a fraction of the solar spectrum that strikes the earth and the energy content of those remaining photons is simply wasted. A strategy to mitigate this problem has been developed over the years in our laboratory. Briefly, photons of low energy are converted into higher energy light using a process termed photon upconversion. Using this technique, low energy photons supplied by the sun can be converted into light of appropriate energy to trigger electronic transitions in high energy absorbing photoactive materials without any chemical modification of the latter. We have shown, that this technology is capable of upconverting visible sunlight to sensitize wide-bandgap semiconductors such as WO
3
, subsequently extending the photoaction of these materials to cover a larger portion of the solar spectrum. Besides the engineering of different compositions that serve as either sensitizers or catalysts in these solar energy conversion schemes, we have designed an apparatus for parallel high-throughput screening of these photocatalytic compositions. This combinatorial approach to solar fuels photocatalysis has already led to unprecedented fundamental understanding of the generation of hydrogen gas from pure water. The activity of a series of new Ru(II) sensitizers along with Co(II) molecular WRCs were optimized under visible light excitation utilizing different experimental conditions. The multi-step mechanism of activity of selected compositions was further elucidated by pump-probe transient absorption spectroscopy.
Committee
Felix Castellano, Dr. (Advisor)
Liangfeng Sun, Dr. (Committee Member)
Ksenija Glusac, Dr. (Committee Member)
Mikhail Zamkov, Dr. (Committee Member)
Pages
191 p.
Subject Headings
Chemistry
;
Materials Science
Keywords
water splitting
;
hydrogen
;
oxygen
;
photocatalysis
;
electrocatalysis
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Citations
Khnayzer, R. S. (2013).
Photocatalytic Water Splitting: Materials Design and High-Throughput Screening of Molecular Compositions
[Doctoral dissertation, Bowling Green State University]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1368627386
APA Style (7th edition)
Khnayzer, Rony.
Photocatalytic Water Splitting: Materials Design and High-Throughput Screening of Molecular Compositions.
2013. Bowling Green State University, Doctoral dissertation.
OhioLINK Electronic Theses and Dissertations Center
, http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1368627386.
MLA Style (8th edition)
Khnayzer, Rony. "Photocatalytic Water Splitting: Materials Design and High-Throughput Screening of Molecular Compositions." Doctoral dissertation, Bowling Green State University, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1368627386
Chicago Manual of Style (17th edition)
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Document number:
bgsu1368627386
Download Count:
3,291
Copyright Info
© 2013, all rights reserved.
This open access ETD is published by Bowling Green State University and OhioLINK.