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Synthesis and Characterization of Titanium Zirconium Based Alloys for Capacitor Use

Corwin, Peter E

Abstract Details

2013, Master of Sciences (Engineering), Case Western Reserve University, Materials Science and Engineering.
This work seeks to characterize a series of Ti-Zr binary alloys and a ternary Ti-Zr-Be alloy as anode materials for electrolytic capacitors. Specifically, this work attempts to improve the electrical behavior by reducing leakage through anodically grown oxide film on binary alloys via microstructure modifications. It also examines creep of Ti25Zr38Be37 metallic glass for surface enhancement. A variety of mechanical and electrical properties were measured. Leakage current through the anodic dielectric was found to decrease with increasing zirconium content. Alloy treatments which produce concentration gradients (a, a+ß fields) increased dielectric leakage; treatments maintaining uniform composition (as cast, wrought) retain low dielectric leakage current. UTS was fit to a solid solution model which compares well with related literature. Estimates of viscosity for Ti25Zr38Be37 metallic glass were made at various temperatures and resulting surface texturing examined. Long term creep rate change was fit to exponential decay with a time constant of 7.9x103s.
Gerhard Welsch (Advisor)
John Lewandowski (Committee Member)
Mark DeGuire (Committee Member)
112 p.

Recommended Citations

Citations

  • Corwin, P. E. (2013). Synthesis and Characterization of Titanium Zirconium Based Alloys for Capacitor Use [Master's thesis, Case Western Reserve University]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=case1363616395

    APA Style (7th edition)

  • Corwin, Peter. Synthesis and Characterization of Titanium Zirconium Based Alloys for Capacitor Use. 2013. Case Western Reserve University, Master's thesis. OhioLINK Electronic Theses and Dissertations Center, http://rave.ohiolink.edu/etdc/view?acc_num=case1363616395.

    MLA Style (8th edition)

  • Corwin, Peter. "Synthesis and Characterization of Titanium Zirconium Based Alloys for Capacitor Use." Master's thesis, Case Western Reserve University, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=case1363616395

    Chicago Manual of Style (17th edition)