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Gold-Nanoparticle Cored Carbazole Functionalized Star-like Copolymer Hybrid Nanomaterial with Tunable Properties

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2018, Master of Sciences, Case Western Reserve University, Macromolecular Science and Engineering.
A series of core-shell inorganic-organic hybrid nanomaterials have been proposed with gold nanoparticle as core, carbazole terminated star-like copolymer (h-PEI-b-PCL-Cbz) as shell which consist of hyper-branched polyethyleneimine (h-PEI) and three different chain lengths of poly(ε-caprolactone) (PCL). Electrostatic interaction between the PEI core and gold nanoparticles provides the possibility to form a core-shell nanomaterial by phase transfer method. By adjusting the degree of polymerization of PCL as well as the chain length of PCL, this core-shell nanomaterial has a controllability of energy transferring property and tunability of surface hydrophobicity as well as ionic probe diffusion property. These properties will help with further applications of formed core-shell hybrid system.
Rigoberto Advincula (Committee Chair)
David Schiraldi (Committee Member)
Lei Zhu (Committee Member)
Alexander Jamieson (Committee Member)
105 p.

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Citations

  • Cheng, X. (2018). Gold-Nanoparticle Cored Carbazole Functionalized Star-like Copolymer Hybrid Nanomaterial with Tunable Properties [Master's thesis, Case Western Reserve University]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=case1522803372777943

    APA Style (7th edition)

  • Cheng, Xiang. Gold-Nanoparticle Cored Carbazole Functionalized Star-like Copolymer Hybrid Nanomaterial with Tunable Properties. 2018. Case Western Reserve University, Master's thesis. OhioLINK Electronic Theses and Dissertations Center, http://rave.ohiolink.edu/etdc/view?acc_num=case1522803372777943.

    MLA Style (8th edition)

  • Cheng, Xiang. "Gold-Nanoparticle Cored Carbazole Functionalized Star-like Copolymer Hybrid Nanomaterial with Tunable Properties." Master's thesis, Case Western Reserve University, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=case1522803372777943

    Chicago Manual of Style (17th edition)