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OPTIMIZATION OF IRIDIUM AND RUTHENIUM CATALYSTS IN THE C-H OXIDATION OF ALKANES

Bode, Kirstin S
http://rave.ohiolink.edu/etdc/view?acc_num=ksuhonors1620909877637546

Abstract Details

2021, BS, Kent State University, College of Arts and Sciences / Department of Chemistry and Biochemistry.
C–H functionalization is a rapidly growing subfield of organic synthesis, and the development of selective, high-yielding oxidation catalysts is of great importance. This research develops a new class of 8-aminoquinoline-based ligands for Ir(III) C–H oxidation catalysts using sodium periodate as an oxidant, optimizes the reaction conditions, and develops a new triple-catalytic oxidation reaction with molecular oxygen as the terminal oxidant. Yields of single oxidation events using sodium periodate were as high as 50%, while use of the triple-catalytic oxidation reaction resulted in yields ranging from 6–30%.
Jeffrey Mighion, Ph.D. (Advisor)
Yaorong Zheng, Ph.D. (Committee Member)
John Portman, Ph.D. (Committee Member)
Alexander Seed, Ph.D. (Committee Member)
34 p.
Chemistry
catalysis; iridium catalyst; oxidation; C-H oxidation

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Citations

  • Bode, K. S. (2021). OPTIMIZATION OF IRIDIUM AND RUTHENIUM CATALYSTS IN THE C-H OXIDATION OF ALKANES [Undergraduate thesis, Kent State University]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=ksuhonors1620909877637546

    APA Style (7th edition)

  • Bode, Kirstin. OPTIMIZATION OF IRIDIUM AND RUTHENIUM CATALYSTS IN THE C-H OXIDATION OF ALKANES. 2021. Kent State University, Undergraduate thesis. OhioLINK Electronic Theses and Dissertations Center, http://rave.ohiolink.edu/etdc/view?acc_num=ksuhonors1620909877637546.

    MLA Style (8th edition)

  • Bode, Kirstin. "OPTIMIZATION OF IRIDIUM AND RUTHENIUM CATALYSTS IN THE C-H OXIDATION OF ALKANES." Undergraduate thesis, Kent State University, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=ksuhonors1620909877637546

    Chicago Manual of Style (17th edition)

ksuhonors1620909877637546
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This open access ETD is published by Kent State University Honors College and OhioLINK.