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miami1155330219.pdf (5.16 MB)
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Abstract Header
SINGLE MOLECULE ELECTRONICS AND NANOFABRICATION OF MOLECULAR ELECTRONIC DEVICES
Author Info
Rajagopal, Senthil Arun
Permalink:
http://rave.ohiolink.edu/etdc/view?acc_num=miami1155330219
Abstract Details
Year and Degree
2006, Master of Science, Miami University, Physics.
Abstract
Molecular electronics is an emerging field that makes it possible to build electronic devices with single molecules as their active element. The conductivity of single molecules can be manipulated to perform functions similar to present-day bulk electronic devices. These single molecules, with a size of few nano-meters, can be designed and chemically synthesized with tailored electronic structures. This thesis focuses on the design, fabrication and measurement of nanogap electronic devices. The enabling device to study the conductivity of dimetal paddlewheel inorganic complexes, using electrode pairs with nanometer separation is fabricated. A study of these inorganic complexes would provide more versatile opportunities for tailoring electron transport properties. The molecular complex and its electron transport mechanism are discussed and a detailed description of the fabrication of the nano-gap electrode with a controlled gap size is provided. Electron beam lithography fabrication techniques are discussed in detail. A reliable method to fabricate a controlled nanogap with electrodeposition and electromigration is demonstrated. The results of I-V curves of gaps are used to estimate the nanogap dimensions via comparison to tunneling current theory.
Committee
Jan Yarrison-Rice (Advisor)
Pages
107 p.
Subject Headings
Physics, Molecular
Keywords
SINGLE MOLECULE ELECTRONICS
;
ORGANOMETALLIC
;
ELECTRON BEAM LITHOGRAPHY
;
ELECTRODEPOSITION
;
ELECTROMIGRATION
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Citations
Rajagopal, S. A. (2006).
SINGLE MOLECULE ELECTRONICS AND NANOFABRICATION OF MOLECULAR ELECTRONIC DEVICES
[Master's thesis, Miami University]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=miami1155330219
APA Style (7th edition)
Rajagopal, Senthil.
SINGLE MOLECULE ELECTRONICS AND NANOFABRICATION OF MOLECULAR ELECTRONIC DEVICES.
2006. Miami University, Master's thesis.
OhioLINK Electronic Theses and Dissertations Center
, http://rave.ohiolink.edu/etdc/view?acc_num=miami1155330219.
MLA Style (8th edition)
Rajagopal, Senthil. "SINGLE MOLECULE ELECTRONICS AND NANOFABRICATION OF MOLECULAR ELECTRONIC DEVICES." Master's thesis, Miami University, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=miami1155330219
Chicago Manual of Style (17th edition)
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Document number:
miami1155330219
Download Count:
1,762
Copyright Info
© 2006, all rights reserved.
This open access ETD is published by Miami University and OhioLINK.