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ohiou1183728633.pdf (8.87 MB)
ETD Abstract Container
Abstract Header
Microwave enhanced chemical vapor deposition of silicon compound thin films and their characterization
Author Info
Gopal, Madan
Permalink:
http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1183728633
Abstract Details
Year and Degree
1991, Master of Science (MS), Ohio University, Chemical Engineering (Engineering).
Abstract
This project involves the study of deposition of silicon compound films using 3 different liquid reactants, namely, tetramethyl silane (TMS), silicon tetrachloride (STC), and hexamethyl disilazane (HMDS), all saturated in nitrogen. The films were characterized with respect to their composition, thickness, structure, and oxidation resistance. The influence of process variables, namely, pressure, deposition geometry, and reactant flow rate/ratio, on the film properties were determined. The effect of annealing on the film thickness and composition was determined. An effort was made to modify the composition by exposing the substrates to a nitrogen plasma for 1 minute before film deposition. The results show major interactions between the pressure, flow rate, and flow geometry in the system. The results seem to be the net effect of gas phase concentration, dissociation, diffusion, and residence time distribution. These were in turn governed by the silicon source compound used. For TMS reactant entry length of 4 inches was optimum. The major constituents of the film were Si, N, O, C, and H. In films produced with STC, chlorine was also detected. The process variables did not influence the composition of the film. The proportion of Si/N was between 0.75 and 1.33. IR spectra show SiCH
3
, SiO, SiNH, and SiN bonds. Nitrogen plasma pre-exposure did not affect the film composition but altered the deposition characteristics. Annealing changed the films essentially to SiO
2
and reduced film thickness. The films exhibited good oxidation properties.
Committee
Daniel Gulino (Advisor)
Pages
140 p.
Subject Headings
Engineering, Chemical
Keywords
Microwave Enhanced Chemical
;
Vapor Deposition
;
Silicon Compound Thin Films
;
Characterization
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Citations
Gopal, M. (1991).
Microwave enhanced chemical vapor deposition of silicon compound thin films and their characterization
[Master's thesis, Ohio University]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1183728633
APA Style (7th edition)
Gopal, Madan.
Microwave enhanced chemical vapor deposition of silicon compound thin films and their characterization.
1991. Ohio University, Master's thesis.
OhioLINK Electronic Theses and Dissertations Center
, http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1183728633.
MLA Style (8th edition)
Gopal, Madan. "Microwave enhanced chemical vapor deposition of silicon compound thin films and their characterization." Master's thesis, Ohio University, 1991. http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1183728633
Chicago Manual of Style (17th edition)
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Document number:
ohiou1183728633
Download Count:
721
Copyright Info
© 1991, all rights reserved.
This open access ETD is published by Ohio University and OhioLINK.