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Investigation of Microbiologically Influenced Corrosion (MIC) and Biocide Treatment in Anaerobic Salt Water and Development of A Mechanistic MIC Model

Abstract Details

2008, Doctor of Philosophy (PhD), Ohio University, Chemical Engineering (Engineering and Technology).

Pipelines during and after hydrotesting are vulnerable to microbiologically influenced corrosion (MIC), which can result in severe pinhole leaks. Instead of the current MIC studies in the field practice, this study investigated the MIC phenomenon in hydrotesting under laboratory conditions, and a variety of issues that arose during this process are discussed.

The MIC process during hydrotesting was found to be dependent on water sources due to different concentrations of nutrients and native organisms. In order to accelerate the MIC process, a simulated worst-case scenario with a lab strain SRB (sulfate-reducing bacteria) and key nutrients added proved to be a useful approach. Furthermore, the technique of polymerase chain reaction (PCR) was adopted to MIC research for detecting very low concentrations of targeted planktonic microbes.

A novel MIC mitigation method, using biocides THPS (TetrakisHydroxymethyl-Phosphonium Sulfate) and glutaraldehyde, in combination with EDTA (Ethylene-DiamineTetraAcetic acid) was found to be more effective for controlling the growth of planktonic SRB. A mechanistic THPS degradation model, with great consistency to experimental results, was developed to predict residual THPS concentration to assure that it does not fall below the desired minimum required for MIC control.

Based on the mechanism of biocatalytic cathodic sulfate reduction (BCSR), a first generation MIC mechanistic model was developed to predict the MIC pitting rate under certain conditions; thus providing a basis for a more comprehensive mechanistic MIC modeling. Futhermore, a new biomarker EPS (extracellular polymeric substances), a potential replacement of existing biofilm probes, was proposed to serve for locating biofilms.

Tingyue Gu, PhD (Advisor)
Srdjan Nesic, PhD (Committee Member)
Darin Ridgway, PhD (Committee Member)
Peter Coschigano, PhD (Committee Member)
Liwei Chen, PhD (Committee Member)
284 p.

Recommended Citations

Citations

  • Zhao, K. (2008). Investigation of Microbiologically Influenced Corrosion (MIC) and Biocide Treatment in Anaerobic Salt Water and Development of A Mechanistic MIC Model [Doctoral dissertation, Ohio University]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1226522833

    APA Style (7th edition)

  • Zhao, Kaili. Investigation of Microbiologically Influenced Corrosion (MIC) and Biocide Treatment in Anaerobic Salt Water and Development of A Mechanistic MIC Model. 2008. Ohio University, Doctoral dissertation. OhioLINK Electronic Theses and Dissertations Center, http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1226522833.

    MLA Style (8th edition)

  • Zhao, Kaili. "Investigation of Microbiologically Influenced Corrosion (MIC) and Biocide Treatment in Anaerobic Salt Water and Development of A Mechanistic MIC Model." Doctoral dissertation, Ohio University, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1226522833

    Chicago Manual of Style (17th edition)