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Structure-Composition-Property Relationships In 5xxx Series Aluminum Alloys

Unocic, Kinga Angelika

Abstract Details

2008, Doctor of Philosophy, Ohio State University, Materials Science and Engineering.
Al-Mg alloys are well suited for marine applications due to their low density, ease of fabrication, structural durability, and most notably resistance to corrosion. The purpose of this study is to investigate the effects of alloying additions, mechanical processing and heat treatments on the development of grain boundary phases that have an effect on intergranular corrosion resistance (IGC). Through modification of the standard AA5083 composition with extra additions of Cu and Zn and in conjunction with a long sensitization heat treatment (in excess of 1000 hrs at 165°C) it is possible to form a corrosion resistance modified τ-phase along grain boundaries. From an economical standpoint it is too costly to heat treat an alloy for such a long period of time and therefore an alternative method of producing a corrosion resistant alloy has been explored. Cu, Zn, and Si modified compositions were produced and were subjected to a high degree of cold work and shorter sensitization times. Following ASTM G67 intergranular corrosion testing and a detailed microstructural characterization, an optimal composition and processing condition that yielded the best intergranular corrosion resistance was determined. The microstructural development that led to these findings and issues with TEM sample preparation will be discussed in detail.
Glenn Daehn, PhD (Advisor)
Michael Mills, PhD (Committee Member)
Buchheit Rudolph, PhD (Committee Member)
Partridge Mark, PhD (Committee Member)

Recommended Citations

Citations

  • Unocic, K. A. (2008). Structure-Composition-Property Relationships In 5xxx Series Aluminum Alloys [Doctoral dissertation, Ohio State University]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=osu1218473077

    APA Style (7th edition)

  • Unocic, Kinga. Structure-Composition-Property Relationships In 5xxx Series Aluminum Alloys. 2008. Ohio State University, Doctoral dissertation. OhioLINK Electronic Theses and Dissertations Center, http://rave.ohiolink.edu/etdc/view?acc_num=osu1218473077.

    MLA Style (8th edition)

  • Unocic, Kinga. "Structure-Composition-Property Relationships In 5xxx Series Aluminum Alloys." Doctoral dissertation, Ohio State University, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=osu1218473077

    Chicago Manual of Style (17th edition)