Skip to Main Content
Frequently Asked Questions
Submit an ETD
Global Search Box
Need Help?
Keyword Search
Participating Institutions
Advanced Search
School Logo
Files
File List
osu1268143515.pdf (3.65 MB)
ETD Abstract Container
Abstract Header
Differential Optical Absorption Spectroscopy of Trace Gas Species and Aerosols in the Upper Ohio River Valley
Author Info
Beekman, Christopher Paul
Permalink:
http://rave.ohiolink.edu/etdc/view?acc_num=osu1268143515
Abstract Details
Year and Degree
2010, Doctor of Philosophy, Ohio State University, Environmental Science.
Abstract
In this research, it is hypothesized that recently developed theoretical considerations of atmospheric radiative transfer in horizontally in-homogeneous atmospheres can be applied to the remote measurement of anthropogenic plumes. To this end, a MAX-DOAS spectrometer, designed around a BandW-TEK BTU142 spectrometer was constructed and characterized. It was found that the MAX-DOAS spectrometer has a measured resolution of 0.282 nm, and a noise level of 178 counts at 75% pixel saturation, sufficient to resolve accurately the absorptions of important atmospheric species, including SO
2
, NO
2
, HCHO, and O
4
. The theory of MAX-DOAS spectral analysis was examined in detail, in particular the processing of reference absorption cross-section spectra for use in regression analyses of scattered solar radiation. For the purposes of inversion, optimal estimation software was designed and investigated for suitability in retrieving vertical profiles of atmospheric species. This software is shown to perform well under conditions of both typical and non-typical noise levels using synthetic spectral data and known profiles of three atmospheric species. Furthermore, an extensive examination of the residuals of DOAS spectral analysis was performed, to validate the assumption of normally distributed errors in the inversion process. Investigated methodologies were applied to spectral data collected over nine days in 2008 in the Upper Ohio River Valley. Aerosol extinction coefficient profiles were successfully retrieved, with an average peak value of 0.549 km
-1
. For the same measurement period, in-plume measurements of SO
2
and NO
2
concentration from a coal-fired power plant were conducted using recently developed methodologies to account for in-plume solar radiative transfer effects.
Committee
Heather Allen, PhD (Advisor)
Catherine Calder, PhD (Committee Member)
Bryan Mark, PhD (Committee Member)
Franklin Schwartz, PhD (Committee Member)
Subject Headings
Environmental Science
Keywords
MAX-DOAS
;
Ohio River Valley
;
power plant plumes
;
air pollution
Recommended Citations
Refworks
EndNote
RIS
Mendeley
Citations
Beekman, C. P. (2010).
Differential Optical Absorption Spectroscopy of Trace Gas Species and Aerosols in the Upper Ohio River Valley
[Doctoral dissertation, Ohio State University]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=osu1268143515
APA Style (7th edition)
Beekman, Christopher.
Differential Optical Absorption Spectroscopy of Trace Gas Species and Aerosols in the Upper Ohio River Valley.
2010. Ohio State University, Doctoral dissertation.
OhioLINK Electronic Theses and Dissertations Center
, http://rave.ohiolink.edu/etdc/view?acc_num=osu1268143515.
MLA Style (8th edition)
Beekman, Christopher. "Differential Optical Absorption Spectroscopy of Trace Gas Species and Aerosols in the Upper Ohio River Valley." Doctoral dissertation, Ohio State University, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=osu1268143515
Chicago Manual of Style (17th edition)
Abstract Footer
Document number:
osu1268143515
Download Count:
640
Copyright Info
© 2010, all rights reserved.
This open access ETD is published by The Ohio State University and OhioLINK.