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Bis(trimethylstannyl)benzopinacolate Promoted Radical Carbon-Carbon Bond Forming Reactions and Related Studies

Seely, Franklin Lee
http://rave.ohiolink.edu/etdc/view?acc_num=osu1290711413

Abstract Details

2010, Doctor of Philosophy, Ohio State University, Chemistry.
This research has dealt primarily with the development of novel methods for radical carbon-carbon bond formation. A major focus of this research has been the hydrogen atom free generation of trialkyltin radicals. The bulk of this thesis will deal with the use of bis(trimethylstannyl)benzopinacolate 1 in mediating radical reactions. We have demonstrated that these conditions allow a wide variety of inter and intramolecular free radical addition reactions. We have given evidence that these reactions proceed via a novel non-chain free radical mechanism.
Robert Coleman, S (Advisor)
David Hart, J (Committee Co-Chair)
T. V. RajanBabu (Committee Member)
Thomas Lemberger, R (Committee Member)
176 p.
Chemistry
organic free radical; non-chain; radical conjugate addition; intermolecular radical; bis(trimethylstannyl)benzopinacolate; free radical; stable free radical; radical one carbon homologation; free radical homologation

Recommended Citations

Citations

  • Seely, F. L. (2010). Bis(trimethylstannyl)benzopinacolate Promoted Radical Carbon-Carbon Bond Forming Reactions and Related Studies [Doctoral dissertation, Ohio State University]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=osu1290711413

    APA Style (7th edition)

  • Seely, Franklin. Bis(trimethylstannyl)benzopinacolate Promoted Radical Carbon-Carbon Bond Forming Reactions and Related Studies. 2010. Ohio State University, Doctoral dissertation. OhioLINK Electronic Theses and Dissertations Center, http://rave.ohiolink.edu/etdc/view?acc_num=osu1290711413.

    MLA Style (8th edition)

  • Seely, Franklin. "Bis(trimethylstannyl)benzopinacolate Promoted Radical Carbon-Carbon Bond Forming Reactions and Related Studies." Doctoral dissertation, Ohio State University, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=osu1290711413

    Chicago Manual of Style (17th edition)

osu1290711413
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© 2010, all rights reserved.
This open access ETD is published by The Ohio State University and OhioLINK.