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Continuum-Scale Modeling of Shear Banding in Bulk Metallic Glass-Matrix Composites

Gibbons, Michael P

Abstract Details

2016, Doctor of Philosophy, Ohio State University, Materials Science and Engineering.
Metallic glasses represent a relatively new class of materials that have demonstrated enormous potential for functional and structural applications due to the unique set of properties attributed to them as a result of the disordered isotropic structure with metallically bonded elements. Amorphous metals benefit from the strong nature of the metallic bonds, but lack the crystallographic structure and polycrystalline nature of traditional metals which unsurprisingly has huge implications on the material properties, as all deformation mechanisms associated with a lattice are suppressed. This results in excellent strength, a high elastic strain limit, exceptional hardness, and improved corrosion and wear resistance. "Bulk" metallic glasses (BMG) represent the amorphous metals which can be produced at the cm length-scale, thus greatly expanding their applicability for structural applications. However, due to the catastrophic nature of the failure produced upon yielding, monolithic metallic glasses are seldomly used for structural applications. Bulk metallic glass-matrix composites (BMGMCs), however, are able to combine the excellent strength, hardness, and elastic strain limit of amorphous metallic glass with a ductile crystalline phase to achieve extraordinary toughness with minimal degradation in strength. In order to explore the mechanical interactions between the amorphous and crystalline phases, a full-field micromechanical model which couples the free-volume based constitutive behavior for the matrix phase with standard rate-dependent crystal plasticity for the dendrites, and its implementation via an elastic-viscoplastic Fast-Fourier Transform (FFT) solver. The model is calibrated to macroscale stress-strain data for Ti-Zr-V-Cu-Be BMGMCs with varying composition and furthermore by comparing the deformation behavior associated with the shear bands predicted by the model, to the artifacts observed from characterization microscopy analysis on the same failed BMGMC tensile specimens in which the macroscopic composite behavior predicted by the model was validated with. The FFT-based deformation modeling is then exercised to study the nature and origin of shear bands in metallic glass composites. Synthetic 3D microstructures were produced using images of real BMGMCs, and then subjected to uniaxial tension deformation simulations. The findings indicate that in BMGMCs, local inhomogeneities in the glass phase are less influential on the mechanical performance than the contrast in individual phase properties and the spatial distribution of the microstructure. Due to the strong contrast in mechanical properties between the phases, highly heterogeneous stress fields develop, contributing to regionally confined free-volume generation, localized flow and softening in the glass. These softened regions can link and plastic flow then rapidly localizes into a thin shear band with planar like geometry. The availability of finely resolved (spatially and temporally) 3D deformation maps allow for the determination of the mechanism corresponding with these macroscopic stick-slip oscillations apparent in the stress-strain curves. In addition to shedding light on the nature of shear banding in bulk metallic glass-matrix composites, this work also demonstrates the feasibility of using a spectral-based continuum-scale model to efficiently predict the microstructure and individual phase properties that lead to new materials, superior to those found using only experimental techniques.
Wolfgang Windl (Advisor)
Stephen Niezgoda (Advisor)
Maryam Ghazisaeidi (Committee Member)
141 p.

Recommended Citations

Citations

  • Gibbons, M. P. (2016). Continuum-Scale Modeling of Shear Banding in Bulk Metallic Glass-Matrix Composites [Doctoral dissertation, Ohio State University]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=osu1471882991

    APA Style (7th edition)

  • Gibbons, Michael. Continuum-Scale Modeling of Shear Banding in Bulk Metallic Glass-Matrix Composites. 2016. Ohio State University, Doctoral dissertation. OhioLINK Electronic Theses and Dissertations Center, http://rave.ohiolink.edu/etdc/view?acc_num=osu1471882991.

    MLA Style (8th edition)

  • Gibbons, Michael. "Continuum-Scale Modeling of Shear Banding in Bulk Metallic Glass-Matrix Composites." Doctoral dissertation, Ohio State University, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=osu1471882991

    Chicago Manual of Style (17th edition)