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toledo1185478138.pdf (2.11 MB)
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Di-(3methylindolyl)methane Complexes of Aluminum and Gallium Alkyls
Author Info
Das, Anirban
Permalink:
http://rave.ohiolink.edu/etdc/view?acc_num=toledo1185478138
Abstract Details
Year and Degree
2007, Master of Science, University of Toledo, Chemistry.
Abstract
This thesis reports the reactions of aluminum and gallium alkyls with two ligands, di(3-methylindolyl)pyridylmethane (L'H2), and di(3-methylindolyl)(1-methylimidazolyl)methane (L''H2). A series of bidentate complexes HLMR2 (L = L', M = Al, Ga, R = tBu; L = L'', M = Al, R = Me, Et, iBu, tBu; L = L'', M = Ga, R = tBu) and a tridentate complex L'GatBu were synthesized. Stoichiometry plays an important role in reactions of L'H2 and L''H2 with Me3Al and Et3Al, as excess of the aluminum alkyl results in the formation of bimetallic complexes LAl2R4 (L= L', L'' ; R = Me, Et). The previously reported bis-aluminum complex, L'Al2Me4 was characterized by X-ray crystallography. This is the first reported example of a group 13 complex with a bridging ì2–ç1:ç1–N indolyl group. The characterization of the new complexes was carried out by 1H, 13C and 2-dimensional NMR spectroscopy as well as X-ray crystallography
Committee
Mark Mason (Advisor)
Pages
101 p.
Subject Headings
Chemistry, Inorganic
Keywords
Indole Bridging aluminum complex
;
Di(3-methylindolyl)methane complexes of aluminum and gallium alkyls
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Citations
Das, A. (2007).
Di-(3methylindolyl)methane Complexes of Aluminum and Gallium Alkyls
[Master's thesis, University of Toledo]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=toledo1185478138
APA Style (7th edition)
Das, Anirban.
Di-(3methylindolyl)methane Complexes of Aluminum and Gallium Alkyls.
2007. University of Toledo, Master's thesis.
OhioLINK Electronic Theses and Dissertations Center
, http://rave.ohiolink.edu/etdc/view?acc_num=toledo1185478138.
MLA Style (8th edition)
Das, Anirban. "Di-(3methylindolyl)methane Complexes of Aluminum and Gallium Alkyls." Master's thesis, University of Toledo, 2007. http://rave.ohiolink.edu/etdc/view?acc_num=toledo1185478138
Chicago Manual of Style (17th edition)
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Document number:
toledo1185478138
Download Count:
1,083
Copyright Info
© 2007, all rights reserved.
This open access ETD is published by University of Toledo and OhioLINK.