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Reaction Mechanism and Detection of Elusive C, N, and O Centered Radicals and Intermediates in Solution and Solid State

Sarkar, Sujan K.
http://rave.ohiolink.edu/etdc/view?acc_num=ucin1448037904

Abstract Details

2015, PhD, University of Cincinnati, Arts and Sciences: Chemistry.
Organic compounds containing a chromophore can be excited from its ground electronic state to higher excited states. This photochemistry of organic compounds can be done in two medium one of which is solution and another is solid state. In solution, the intermediates can be stabilized by solvent molecules and can also freely rotate and thus most of the time there is a loss of stereochemistry. Whereas in solid state due to restricted rotation of the intermediates in the crystal lattice, the stereochemistry is intact. Thus there is much more interest in the solid state photochemistry. To understand the mechanism in solid state it is much needed to identify the intermediates formed in solid state.
Anna Gudmundsdottir, Ph.D. (Committee Chair)
Sivaramakrishnan Muthukrishnan, Ph.D. (Committee Member)
Hairong Guan, Ph.D. (Committee Member)
James Mack, Ph.D. (Committee Member)
673 p.
Organic Chemistry
Solid State Kinetics; Vinyl Nitrene; Laser Flash Photolysis; Photoremovable Protecting Group; ESR Spectroscopy; Matrix Isolation

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Citations

  • Sarkar, S. K. (2015). Reaction Mechanism and Detection of Elusive C, N, and O Centered Radicals and Intermediates in Solution and Solid State [Doctoral dissertation, University of Cincinnati]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1448037904

    APA Style (7th edition)

  • Sarkar, Sujan. Reaction Mechanism and Detection of Elusive C, N, and O Centered Radicals and Intermediates in Solution and Solid State. 2015. University of Cincinnati, Doctoral dissertation. OhioLINK Electronic Theses and Dissertations Center, http://rave.ohiolink.edu/etdc/view?acc_num=ucin1448037904.

    MLA Style (8th edition)

  • Sarkar, Sujan. "Reaction Mechanism and Detection of Elusive C, N, and O Centered Radicals and Intermediates in Solution and Solid State." Doctoral dissertation, University of Cincinnati, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1448037904

    Chicago Manual of Style (17th edition)

ucin1448037904
301
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This open access ETD is published by University of Cincinnati and OhioLINK.