Skip to Main Content
Frequently Asked Questions
Submit an ETD
Global Search Box
Need Help?
Keyword Search
Participating Institutions
Advanced Search
School Logo
Files
File List
R Stuck Thesis Final Document May 2017.pdf (2.84 MB)
ETD Abstract Container
Abstract Header
The Synthesis of 3,5-Difluorobenzophenone Derivatives and their Corresponding PEEK Copolymers
Author Info
Stuck, Rachael
ORCID® Identifier
http://orcid.org/0000-0001-6976-4461
Permalink:
http://rave.ohiolink.edu/etdc/view?acc_num=wright1495148939065733
Abstract Details
Year and Degree
2017, Master of Science (MS), Wright State University, Chemistry.
Abstract
Poly(aryl ether ketone)s (PAEK) are high performance thermoplastics, which are chemically robust, semi-crystalline, and stable at high temperatures. Of the family of PAEKs, poly(ether ether ketone) (PEEK) is a well-known semi-crystalline thermoplastic widely used for electronics, energy, industrial, and medical applications due to its resistance to solvents, radiation, heat, and other environmental factors. The traditional PEEK is prepared from 4,4’-difluorobenzophenone (2) and disodium hydroquinone. However, a challenge is processability, since due to its highly crystalline nature, PEEK possesses very limited solubility. An approach to solve these issues is to pre-functionalize PEEK polymers synthesized by nucleophilic aromatic substitution from 3,5-difluorobenzophenone (1) and hydroquinone, which results in a pendant benzoyl group. By using varying ratios of 3,5-difluorobenzophenone (1) and 4,4’-difluorobenzophenone (2) the degree of crystallinity in the polymer can be tailored. Herein, a series of semi-crystalline PEEK analogues bearing functional groups on the pendant benzoyl moiety, were synthesized and characterized in order to investigate the effects of structural variances on the thermal and solubility behavior.
Committee
Eric Fossum, Ph.D. (Advisor)
Daniel Ketcha, Ph.D. (Committee Member)
Kenneth Turnbull, Ph.D. (Committee Member)
Pages
85 p.
Subject Headings
Chemistry
Keywords
chemistry
Recommended Citations
Refworks
EndNote
RIS
Mendeley
Citations
Stuck, R. (2017).
The Synthesis of 3,5-Difluorobenzophenone Derivatives and their Corresponding PEEK Copolymers
[Master's thesis, Wright State University]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=wright1495148939065733
APA Style (7th edition)
Stuck, Rachael.
The Synthesis of 3,5-Difluorobenzophenone Derivatives and their Corresponding PEEK Copolymers.
2017. Wright State University, Master's thesis.
OhioLINK Electronic Theses and Dissertations Center
, http://rave.ohiolink.edu/etdc/view?acc_num=wright1495148939065733.
MLA Style (8th edition)
Stuck, Rachael. "The Synthesis of 3,5-Difluorobenzophenone Derivatives and their Corresponding PEEK Copolymers." Master's thesis, Wright State University, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=wright1495148939065733
Chicago Manual of Style (17th edition)
Abstract Footer
Document number:
wright1495148939065733
Download Count:
571
Copyright Info
© 2017, all rights reserved.
This open access ETD is published by Wright State University and OhioLINK.