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Decomposition of Novel Diazosugars: Effects on Regioselectivity

Malich, Ashley M.
http://rave.ohiolink.edu/etdc/view?acc_num=ysu1222195006

Abstract Details

2008, Master of Science in Chemistry, Youngstown State University, Department of Chemistry.
The following work describes the construction and decomposition of azidodeoxy sugars with diazoesters attached. The fate of the projected carbeniod intermediate formed in the presence of a rhodium(II) catalyst resulted in the products of inter- and intramolecular imine formation however, no C-H insertion onto the furanose platform was observed. This research also led to the formation of ketone derivatives and dimeric ethers.
Peter Norris, PhD (Advisor)
John A. Jackson, PhD (Committee Member)
Michael A. Serra, PhD (Committee Member)
162 p.
Chemistry; Organic Chemistry
diazosugars; decomposition chemistry; rhodium catalyst; xylose

Recommended Citations

Citations

  • Malich, A. M. (2008). Decomposition of Novel Diazosugars: Effects on Regioselectivity [Master's thesis, Youngstown State University]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1222195006

    APA Style (7th edition)

  • Malich, Ashley. Decomposition of Novel Diazosugars: Effects on Regioselectivity. 2008. Youngstown State University, Master's thesis. OhioLINK Electronic Theses and Dissertations Center, http://rave.ohiolink.edu/etdc/view?acc_num=ysu1222195006.

    MLA Style (8th edition)

  • Malich, Ashley. "Decomposition of Novel Diazosugars: Effects on Regioselectivity." Master's thesis, Youngstown State University, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1222195006

    Chicago Manual of Style (17th edition)

ysu1222195006
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© 2008, all rights reserved.
This open access ETD is published by Youngstown State University and OhioLINK.