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Pekar with signature.pdf (3.69 MB)
ETD Abstract Container
Abstract Header
The Gas-Phase Ligand Exchange of Palladium Beta-diketonate Complexes
Author Info
Pekar, Jennifer Christina
Permalink:
http://rave.ohiolink.edu/etdc/view?acc_num=ysu1410910663
Abstract Details
Year and Degree
2014, Master of Science in Chemistry, Youngstown State University, Department of Chemistry.
Abstract
A series of gas-phase reactions were performed via co-sublimation using a triple quadrupole electron impact mass spectrometer. Novel palladium ß-diketonate complexes, along with several other species containing different metals and ligands were synthesized and observed to readily undergo ligand exchange in the gas phase and are reported herein for the first time. Selective reactions were also conducted involving Pd and Ni complexes utilizing the collision cell of the mass spectrometer as a reaction vessel. Results from these gas-phase reactions shed light on the mechanism of ligand exchange for this class of metal ß-diketonate complexes.
Committee
Brian Leskiw, Ph.D. (Advisor)
Howard Mettee, Ph.D. (Committee Member)
Ganesaratnam Balendiran, Ph.D. (Committee Member)
Pages
153 p.
Subject Headings
Analytical Chemistry
;
Chemistry
;
Gases
;
Inorganic Chemistry
;
Physical Chemistry
Keywords
gas-phase, mass spectrometry, physical, analytical, inorganic, ligand, exchange, palladium, beta-diketonate
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Citations
Pekar, J. C. (2014).
The Gas-Phase Ligand Exchange of Palladium Beta-diketonate Complexes
[Master's thesis, Youngstown State University]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1410910663
APA Style (7th edition)
Pekar, Jennifer.
The Gas-Phase Ligand Exchange of Palladium Beta-diketonate Complexes.
2014. Youngstown State University, Master's thesis.
OhioLINK Electronic Theses and Dissertations Center
, http://rave.ohiolink.edu/etdc/view?acc_num=ysu1410910663.
MLA Style (8th edition)
Pekar, Jennifer. "The Gas-Phase Ligand Exchange of Palladium Beta-diketonate Complexes." Master's thesis, Youngstown State University, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1410910663
Chicago Manual of Style (17th edition)
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Document number:
ysu1410910663
Download Count:
168
Copyright Info
© 2014, all rights reserved.
This open access ETD is published by Youngstown State University and OhioLINK.