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Rhodium-Catalyzed Decomposition of Carbohydrate Diazo Esters

LaLama, Matthew
http://orcid.org/0000-0001-9051-5355
http://rave.ohiolink.edu/etdc/view?acc_num=ysu1532881612843223

Abstract Details

2018, Master of Science in Chemistry, Youngstown State University, Department of Chemistry.
This thesis herein reports the synthesis of two diazo ester sugars and their decomposition in the presence of catalytic rhodium acetate dimer. Reactions were designed for the isolation of products formed through intramolecular C-H insertion reactions. However, no C-H insertion occurred, and instead this research led to the formation of a head-to-head- imine linked dimer not presently reported by previous lab members.
Peter Norris, PhD (Advisor)
Douglas Genna, PhD (Committee Member)
John Jackson, PhD (Committee Member)
101 p.
Chemistry; Organic Chemistry
Rhodium; Catalysis; Azide; Natural product synthesis; Carbohydrate; Diazo

Recommended Citations

Citations

  • LaLama, M. (2018). Rhodium-Catalyzed Decomposition of Carbohydrate Diazo Esters [Master's thesis, Youngstown State University]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1532881612843223

    APA Style (7th edition)

  • LaLama, Matthew. Rhodium-Catalyzed Decomposition of Carbohydrate Diazo Esters. 2018. Youngstown State University, Master's thesis. OhioLINK Electronic Theses and Dissertations Center, http://rave.ohiolink.edu/etdc/view?acc_num=ysu1532881612843223.

    MLA Style (8th edition)

  • LaLama, Matthew. "Rhodium-Catalyzed Decomposition of Carbohydrate Diazo Esters." Master's thesis, Youngstown State University, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1532881612843223

    Chicago Manual of Style (17th edition)

ysu1532881612843223
584
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This open access ETD is published by Youngstown State University and OhioLINK.