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Strozier Final 4232020 with cert.pdf (2.76 MB)

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Halogen Mediated De-Interpenetration of Interpenetrated Zn Metal Organic Frameworks

Strozier , Joseph Lee , Jr.
http://rave.ohiolink.edu/etdc/view?acc_num=ysu1587657198606781

Abstract Details

2020, Master of Science in Chemistry, Youngstown State University, Department of Chemistry.
The synthesis of non-functionalized IRMOF-10 is difficult due to the requirement for highly dilute conditions to prevent interpenetration. Here I report the synthesis of IRMOF-10 via the halogen mediated deinterpenetration of IRMOF-9. Although powder X-ray data is insufficient to differentiate between the MOFs IRMOF-9 and IRMOF-10 the transformation has been confirmed through additional means such as size exclusion dying, where one dye will be incorporated into one MOF and not the other, and density separation. Additionally, the role of different preparations of IRMOF-9 was studied, where I compare different syntheses of IRMOF-9 to see if there would be any changes when deinterpenetrating to IRMOF-10. Lastly the deinterpenetration of MOF-14 to MOF-143 was attempted.
Douglas Genna, PhD (Advisor)
Chris Arntsen, PhD (Committee Member)
Allen Hunter, PhD (Committee Member)
56 p.
Chemistry; Inorganic Chemistry; Organic Chemistry; Polymers

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Citations

  • Strozier , Jr., J. L. (2020). Halogen Mediated De-Interpenetration of Interpenetrated Zn Metal Organic Frameworks [Master's thesis, Youngstown State University]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1587657198606781

    APA Style (7th edition)

  • Strozier , Jr., Joseph. Halogen Mediated De-Interpenetration of Interpenetrated Zn Metal Organic Frameworks. 2020. Youngstown State University, Master's thesis. OhioLINK Electronic Theses and Dissertations Center, http://rave.ohiolink.edu/etdc/view?acc_num=ysu1587657198606781.

    MLA Style (8th edition)

  • Strozier , Jr., Joseph. "Halogen Mediated De-Interpenetration of Interpenetrated Zn Metal Organic Frameworks." Master's thesis, Youngstown State University, 2020. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1587657198606781

    Chicago Manual of Style (17th edition)

ysu1587657198606781
265
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This open access ETD is published by Youngstown State University and OhioLINK.