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On Probabilistic Transition Rates Used in Markov Models for Pitting Corrosion

Workman, Michael

Abstract Details

2014, Master of Science, University of Akron, Applied Mathematics.
A stochastic initiation and propagation model is developed to predict the effects of pitting corrosion on susceptible metals. The model relies upon an inhomogeneous Markov chain system in order to describe the propagation of pit depths throughout a discretized set of states. This work mainly examines the flexibility of the model with respect to the probabilistic transition rates λi used in the Markov system. Depending on the form of λi, either an analytical or a numerical solution procedure can be used to solve the Markov system, with the numerical form of λi being able to simulate a wider variety of systems, especially for dynamically changing environments. By modifying the expression of λi, increases or decreases, cyclical changes, or abrupt shifts in environmental corrosivity are studied. Simplifications to the model are also suggested for the sake of computational efficiency. A tool in the form of a Mathematica Computational Document is offered as an example of the model's possible use in industry. Additionally, suggestions are made in regard to metastable pitting and situations where the metal begins in a corroded state. The model is flexible enough to handle these scenarios as long as appropriate data is available.
Nao Mimoto, Dr. (Advisor)
Curtis Clemons, Dr. (Advisor)
Kevin Kreider, Dr. (Advisor)
Gerald Young, Dr. (Advisor)
96 p.

Recommended Citations

Citations

  • Workman, M. (2014). On Probabilistic Transition Rates Used in Markov Models for Pitting Corrosion [Master's thesis, University of Akron]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=akron1396448113

    APA Style (7th edition)

  • Workman, Michael. On Probabilistic Transition Rates Used in Markov Models for Pitting Corrosion. 2014. University of Akron, Master's thesis. OhioLINK Electronic Theses and Dissertations Center, http://rave.ohiolink.edu/etdc/view?acc_num=akron1396448113.

    MLA Style (8th edition)

  • Workman, Michael. "On Probabilistic Transition Rates Used in Markov Models for Pitting Corrosion." Master's thesis, University of Akron, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=akron1396448113

    Chicago Manual of Style (17th edition)