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Optoelectronic Simulation of Perovskite, All Back Contact, Metasurface Photovoltaic Devices

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2022, Master of Science (MS), Bowling Green State University, Physics.
While Silicon photovoltaic (PV) cells have been the workhorse of solar power generation, many different PV technologies will need to be employed to achieve a greener energy future. One promising emerging technology is Perovskite solar cells, which have demonstrated >25% power conversion efficiency (PCE) with only a decade of research. It has been found that this material also has desirable properties for another emerging technology: All-Back-Contact (ABC) thin-film PV devices. This work investigates Perovskite absorbers in two different ABC designs: Quasi-Interdigitated Back Contact (QIBC) and Metasurface Lattice Back Contact (MSLBC) consisting of a periodic array of photo-absorbing cylinders. Due to the similarity to MSLBC designs, a Metasurface Perfect Absorber (MSPA) was also investigated. The optoelectronic performance of these devices was simulated using COMSOL Multiphysics®, which uses the finite element method to solve sets partial differential equations. It was found that a textured front surface for the QIBC device provides superior optical absorption over a flat front surface at higher wavelengths due to light trapping and optical resonance. Despite the inferior optical performance, the flat front surface QIBC design was shown to achieve a PCE >23%. The MSPA design was found to have high absorption for a wide range of incident angles due to Mie resonance within the periodic cylindrical structures. Strong absorption was also observed in the MSLBC device due again to Mie resonance. The PCE of this device was found to be superior under bottom illumination with room for improvement. Optimization of this design was performed by targeting the cylinder diameter and cylinder height. By comparing the optical and electronic performance for a wide range of these parameters, optimal values were found. The bifacial performance of this device was then examined and it showed little improvement over single-side illumination.
Marco Nardone, Ph.D. (Committee Chair)
Alexey Zayak, Ph.D. (Committee Member)
Haowen Xi, Ph.D. (Committee Member)
67 p.

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Citations

  • Sibila, M. (2022). Optoelectronic Simulation of Perovskite, All Back Contact, Metasurface Photovoltaic Devices [Master's thesis, Bowling Green State University]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1656510941915852

    APA Style (7th edition)

  • Sibila, Matthew. Optoelectronic Simulation of Perovskite, All Back Contact, Metasurface Photovoltaic Devices. 2022. Bowling Green State University, Master's thesis. OhioLINK Electronic Theses and Dissertations Center, http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1656510941915852.

    MLA Style (8th edition)

  • Sibila, Matthew. "Optoelectronic Simulation of Perovskite, All Back Contact, Metasurface Photovoltaic Devices." Master's thesis, Bowling Green State University, 2022. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1656510941915852

    Chicago Manual of Style (17th edition)