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Chiral Calixarenes as Modifiers of Stationary and Mobile Phases in HPLC

Sullenberger, Michael
http://rave.ohiolink.edu/etdc/view?acc_num=ysu1001956187

Abstract Details

2000, Master of Science in Chemistry, Youngstown State University, Department of Chemistry.
The class of basket-shaped macrocyclic componds known as calix[n]arenes are of interest in chromatography due to their ability to form host/guest complexes. An area of limited exploration has been the use of chiral calixarenes to perform analytical separations of enantiomers. The interest in this work arises from the search for alternatives to cyclodextrins, which are used predominantly in the separation of enantiomeric mixtures. Two approaches using calixarenes are presented here. The first is the use of a synthesized chiral calixarene as a modifier of a reverse phase stationary phase in HPLC; the second is the use of the same calixarene as a modifier of the mobile phase in reverse phase HPLC. Interactions between a non-chiral homologous series of compounds and the synthesized calixarene were determined to take place during both approaches. This was evidenced by the difference in retention times, capacity factors, and asymmetry factors when the synthesized calixarene was used as a modifier.
James Mike (Advisor)
49 p.
Chemistry, General
calixarenes

Recommended Citations

Citations

  • Sullenberger, M. (2000). Chiral Calixarenes as Modifiers of Stationary and Mobile Phases in HPLC [Master's thesis, Youngstown State University]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1001956187

    APA Style (7th edition)

  • Sullenberger, Michael. Chiral Calixarenes as Modifiers of Stationary and Mobile Phases in HPLC. 2000. Youngstown State University, Master's thesis. OhioLINK Electronic Theses and Dissertations Center, http://rave.ohiolink.edu/etdc/view?acc_num=ysu1001956187.

    MLA Style (8th edition)

  • Sullenberger, Michael. "Chiral Calixarenes as Modifiers of Stationary and Mobile Phases in HPLC." Master's thesis, Youngstown State University, 2000. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1001956187

    Chicago Manual of Style (17th edition)

ysu1001956187
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© 2000, all rights reserved.
This open access ETD is published by Youngstown State University and OhioLINK.