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Silvestri Dominic PDF A APPROVED.pdf (2.87 MB)
ETD Abstract Container
Abstract Header
The Gas Phase Ligand Exchange of Cadmium ß-diketonate Complexes
Author Info
Silvestri, Dominic
Permalink:
http://rave.ohiolink.edu/etdc/view?acc_num=ysu1409754481
Abstract Details
Year and Degree
2014, Master of Science in Chemistry, Youngstown State University, Department of Chemistry.
Abstract
A series of gas-phase ligand exchange reactions involving Cadmium trifluorotrimethylacetylacetonate (Cd(tftm)
2
) were examined using a triple quadrupole mass spectrometer. Multiple co-sublimation experiments were explored with various metal ß-diketonates where several partial and complete ligand exchange processes were observed and are reported herein for the first time. In an attempt to elucidate possible mechanisms leading to the formation of the mixed ligand complex, select ion-neutral experiments were conducted within the collision cell of the triple quadrupole mass spectrometer.
Committee
Brian Leskiw, PhD (Advisor)
Howard Mettee, PhD (Committee Member)
Ganesaratnam Balendiran, PhD (Committee Member)
Pages
133 p.
Subject Headings
Analytical Chemistry
;
Chemistry
;
Inorganic Chemistry
;
Physical Chemistry
Keywords
Gas Phase Reaction
;
Ligand Exchange
;
Beta-diketonates
;
Cadmium complexes
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Citations
Silvestri, D. (2014).
The Gas Phase Ligand Exchange of Cadmium ß-diketonate Complexes
[Master's thesis, Youngstown State University]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1409754481
APA Style (7th edition)
Silvestri, Dominic.
The Gas Phase Ligand Exchange of Cadmium ß-diketonate Complexes.
2014. Youngstown State University, Master's thesis.
OhioLINK Electronic Theses and Dissertations Center
, http://rave.ohiolink.edu/etdc/view?acc_num=ysu1409754481.
MLA Style (8th edition)
Silvestri, Dominic. "The Gas Phase Ligand Exchange of Cadmium ß-diketonate Complexes." Master's thesis, Youngstown State University, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1409754481
Chicago Manual of Style (17th edition)
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Document number:
ysu1409754481
Download Count:
129
Copyright Info
© 2014, all rights reserved.
This open access ETD is published by Youngstown State University and OhioLINK.