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Full text release has been delayed at the author's request until September 01, 2025

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The Gas-Phase Ligand Exchange of Select Metal Bis-diisopropylacetylacetonate Complexes

Boulos, Victoria Marie
http://rave.ohiolink.edu/etdc/view?acc_num=ysu1503671099629922

Abstract Details

2017, Master of Science in Chemistry, Youngstown State University, Department of Chemistry.
A series of gas-phase reactions were performed via co-sublimation within a triple quadrupole electron impact mass spectrometer. Novel alkaline earth and transition metal bis-diisopropylacetylacetonate coordination complexes were synthesized and observed to undergo gas-phase ligand exchange with select alkaline earth and transition metal bis-acetylacetonate and bis-trifluorotrimethylacetylacetonate complexes, and are reported herein for the first time. Also, novel alkaline earth and transition metal coordination compounds were characterized via x-ray crystallography. The results from these gas-phase experiments further establish the foundation of ligand exchange for this class of compounds.
Brian Leskiw, PhD (Advisor)
Howard Mettee, PhD (Committee Member)
Sherri Lovelace-Cameron, PhD (Committee Member)
378 p.
Analytical Chemistry; Chemistry; Inorganic Chemistry; Physical Chemistry
gas-phase; ligand exchange; beta-diketonate complexes

Recommended Citations

Citations

  • Boulos, V. M. (2017). The Gas-Phase Ligand Exchange of Select Metal Bis-diisopropylacetylacetonate Complexes [Master's thesis, Youngstown State University]. OhioLINK Electronic Theses and Dissertations Center. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1503671099629922

    APA Style (7th edition)

  • Boulos, Victoria . The Gas-Phase Ligand Exchange of Select Metal Bis-diisopropylacetylacetonate Complexes. 2017. Youngstown State University, Master's thesis. OhioLINK Electronic Theses and Dissertations Center, http://rave.ohiolink.edu/etdc/view?acc_num=ysu1503671099629922.

    MLA Style (8th edition)

  • Boulos, Victoria . "The Gas-Phase Ligand Exchange of Select Metal Bis-diisopropylacetylacetonate Complexes." Master's thesis, Youngstown State University, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1503671099629922

    Chicago Manual of Style (17th edition)

ysu1503671099629922
© 2017, all rights reserved.
This open access ETD is published by Youngstown State University and OhioLINK.